Home >Pharmaceutical > CH3OOH
- Chemical Name: CH3OOH
- CAS No.: 3031-73-0
CH3OOH Good Manufacturer supply High Quality 3031-73-0
- Molecular Formula: CH4 O2
- Molecular Weight: 48.0416
- Melting Point: -72°C
- Refractive Index: 1.3290 (estimate)
- Boiling Point: 78.1°Cat760mmHg
- PKA: 11.25±0.10(Predicted)
- Flash Point: 1.1°C
- PSA： 29.46000
- Density: 0.982g/cm3
- LogP: 0.10580
3031-73-0 Relevant articles
Fourier Transform Infrared Studies of the Self-Reaction of CH3O2 Radicals
Niki, H.,Maker, P. D.,Savage, C. M.,Breitenbach, L. P.
, p. 877 - 881 (1981)
Product studies were made with the FT IR...
A product yield study of the reaction of HO2 radicals with ethyl peroxy (C2H5O2), acetyl peroxy (CH3C(O)O2), and acetonyl peroxy (CH3C(O)CH2O2) radicals
Hasson, Alam S.,Tyndall, Geoffrey S.,Orlando, John J.
, p. 5979 - 5989 (2004)
Branching ratios for HO2 and RO2 reactio...
Catalytic oxidation of methane to methyl hydroperoxide and other oxygenates under mild conditions
Nizova, Galina V.,Suess-Fink, Georg,Shul'pin, Georgiy B.
, p. 397 - 398 (1997)
Methane is oxidized by air in acetonitri...
Selective oxidation of methane to methanol using AuPd@ZIF-8
Sun, Chenghua,Xu, Guowang,Xu, Yongjun,Yu, Aimin
, (2021)
Selective methane conversion to alcohol ...
Insights into the direct selective oxidation of methane to methanol over ZSM-5 zeolytes in aqueous hydrogen peroxide
Al-Megren, Hamid,Al-Shihri, Saeed,Chadwick, David,Richard, Christian J.
, p. 269 - 278 (2020)
The direct selective oxidation of methan...
Formation of Molecular Hydrogen by Thermal Decomposition of n-Dialkyl Peroxides in Oxygen
Sahetchian, K. A.,Heiss, A.,Rigny, R.
, p. 2382 - 2386 (1987)
The decomposition of low concentrations ...
FTIR Study of the Kinetics and Mechanism for Cl-Atom-Initiated Reactions of Acetaldehyde
Niki, H.,Maker. P. D.,Savage, C. M.,Breitenbach, L. P.
, p. 588 - 591 (1985)
The rate constant for the reaction Cl + ...
Cu single-atoms embedded in porous carbon nitride for selective oxidation of methane to oxygenates
Wu, Bo,Yang, Ruoou,Shi, Lei,Lin, Tiejun,Yu, Xing,Huang, Min,Gong, Kun,Sun, Fanfei,Jiang, Zheng,Li, Shenggang,Zhong, Liangshu,Sun, Yuhan
, p. 14677 - 14680 (2020)
Cu single atoms embedded in the C3N4 (Cu...
High-Pressure Falloff Curves and Specific Rate Constants for the Reaction CH3 + O2 CH3O2 CH3O + O
Cobos, C. J.,Hippler, H.,Luther, K.,Ravishankara, A. R.,Troe, J.
, p. 4332 - 4338 (1985)
The recombination reaction CH3 + O2 -> C...
Flash Photolysis Study of the CH3O2 + HO2 Reaction between 248 to 573 K
Lightfoot, P. D.,Veyret, B.,Lesclaux, R.
, p. 708 - 714 (1990)
The kinetics of the reaction CH3O2 + HO2...
Oxidation of a Monomethylpalladium(II) Complex with O2 in Water: Tuning Reaction Selectivity to Form Ethane, Methanol, or Methylhydroperoxide
Sberegaeva, Anna V.,Zavalij, Peter Y.,Vedernikov, Andrei N.
, p. 1446 - 1455 (2016)
Photochemical aerobic oxidation of n-Pr4...
Experimental confirmation of the low-temperature oxidation scheme of alkanes
Battin-Leclerc, Frederique,Herbinet, Olivier,Glaude, Pierre-Alexandre,Fournet, Rene,Zhou, Zhongyue,Deng, Liulin,Guo, Huijun,Xie, Mingfeng,Qi, Fei
, p. 3169 - 3172 (2010)
(Chemical equation presented) Intermedia...
Oxygenation of methane with atmospheric oxygen in aqueous solution promoted by H2O2 and catalyzed by a vanadate ion-pyrazine-2-carboxylic acid system
Suess-Fink,Yan', Hong,Nizova,Stanislas,Shul'pin
, p. 1801 - 1803 (1997)
Methane is oxidized in aqueous solution ...
FTIR product study of the reactions CH3O2 + CH3O2 and CH3O2 + O3
Tyndall,Wallington,Ball
, p. 2547 - 2554 (1998)
The products of the self-reaction of met...
Unprecedentedly high efficiency for photocatalytic conversion of methane to methanol over Au-Pd/TiO2-what is the role of each component in the system?
Cai, Xiaojiao,Fang, Siyuan,Hu, Yun Hang
, p. 10796 - 10802 (2021)
Direct and highly efficient conversion o...
-
Gray
, p. 3150,3152 (1952)
-
A Supported Nickel Catalyst Stabilized by a Surface Digging Effect for Efficient Methane Oxidation
Zhou, Huang,Liu, Tianyang,Zhao, Xuyan,Zhao, Yafei,Lv, Hongwei,Fang, Shi,Wang, Xiaoqian,Zhou, Fangyao,Xu, Qian,Xu, Jie,Xiong, Can,Xue, Zhenggang,Wang, Kai,Cheong, Weng-Chon,Xi, Wei,Gu, Lin,Yao, Tao,Wei, Shiqiang,Hong, Xun,Luo, Jun,Li, Yafei,Wu, Yuen
, p. 18388 - 18393 (2019)
A surface digging effect of supported Ni...
Reactive Channels of the CH3O2-CH3O2 Reaction
Kan, Charles S.,Calvert, Jack G.,Shaw, John H.
, p. 3411 - 3417 (1980)
Kinetic studies of the products of the C...
Low-temperature direct conversion of methane to methanol over carbon materials supported Pd-Au nanoparticles
He, Yingluo,Luan, Chunhui,Fang, Yuan,Feng, Xiaobo,Peng, Xiaobo,Yang, Guohui,Tsubaki, Noritatsu
, p. 48 - 53 (2020)
Direct conversion of methane to methanol...
Binary Au–Cu Reaction Sites Decorated ZnO for Selective Methane Oxidation to C1 Oxygenates with Nearly 100% Selectivity at Room Temperature
Gong, Zhuyu,Liu, Huifen,Luo, Lei,Ma, Jiani,Tang, Junwang,Xing, Jialiang,Xu, Youxun
supporting information, p. 740 - 750 (2022/01/03)
Direct and efficient oxidation of methan...
Oxidation of methane to methanol over Pd@Pt nanoparticles under mild conditions in water
Chen, Jianjun,Chen, Yaoqiang,Collière, Vincent,Lecante, Pierre,Peres, Laurent,Philippot, Karine,Wang, Sikai,Yan, Ning
, p. 3493 - 3500 (2021/06/06)
Direct methane oxidation into oxygen-con...
Lanthanum modified Fe-ZSM-5 zeolites for selective methane oxidation with H2O2
Barnes, Alexandra J.,Bere, Takudzwa,Dummer, Nicholas F.,Gong, Xiaoxiao,Hutchings, Graham J.,Lewis, Richard J.,Morgan, David J.,Richards, Nia,Shaw, Greg,Sun, Songmei
, p. 8052 - 8064 (2021/12/27)
Selective partial oxidation of methane t...
3031-73-0 Process route
-
-
624-83-9
methyl isocyanate
-
-
3031-73-0
methyl hydroperoxide
-
-
57-12-5
cyanide(1-)
-
-
71000-82-3
cyanate
-
-
C2 H3 NO2 (1-)
| Conditions | Yield |
|---|---|
|
With
hydroperoxide anion;
In
gaseous matrix;
at 26.9 ℃;
Rate constant;
Product distribution;
in a flowing afterglow system (flow rector affixed to a quadrupole mass spectrometer);
|
-
-
34557-54-5,27936-85-2
methane
-
-
50-00-0,30525-89-4,61233-19-0
formaldehyd
-
-
64-18-6
formic acid
-
-
3031-73-0
methyl hydroperoxide
| Conditions | Yield |
|---|---|
|
With
2-pyrazylcarboxylic acid; air; dihydrogen peroxide; [n-Bu4N]VO3;
In
acetonitrile;
at 23 - 75 ℃;
Product distribution;
Mechanism;
oxidation in glass-lined stainless steel autoclave;
|
|
|
With
air; dihydrogen peroxide;
2-pyrazylcarboxylic acid; [n-Bu4N]VO3;
In
acetonitrile;
at 40 ℃;
for 4h;
Product distribution;
various temp. and time;
|
|
|
With
sodium vanadate; air; 2,3,4,5,6-pentachloroaniline; dihydrogen peroxide;
In
water;
at 100 ℃;
Product distribution;
other temperature, time dependence; also in the absence of catalyst;
|
3031-73-0 Upstream products
-
2143-68-2
methoxyl radical
-
2143-58-0
methylperoxy radical
-
34557-54-5
methane
-
4143-42-4
(Z )-azomethane
3031-73-0 Downstream products
-
50-00-0
formaldehyd
-
2143-58-0
methylperoxy radical
-
74087-87-9
hydroperoxymethyl radical
-
106-34-3
quinhydrone