Home >Pharmaceutical> TRI-N-OCTYLALUMINIUM
- Chemical Name:TRI-N-OCTYLALUMINIUM
- CAS No.:1070-00-4
Quality products?make an important contribution to long-term revenue and profitability. Cost-effective and customizable TRI-N-OCTYLALUMINIUM 1070-00-4 supplier
1.What is the TRI-N-OCTYLALUMINIUM ?
Polyolefin catalyst.
-
-
aluminium hydride
-
-
111-66-0,25068-25-1
oct-1-ene
-
-
1070-00-4
trioctylaluminum
| Conditions | Yield |
|---|---|
|
In
octane;
under N2 or Ar; suspn. of (AlH3)(n) in octane heated to 120°C; olefin (1 equiv.) added dropwise; after 30 min temp. raised to 125°C (reflux); cooled to 100-110°C; olefin (2.1 equiv.) added over 3-4 h; kept (90-100°C, 1 h); cooled; filtered through glass filter; solvent amd excess olefin distd. off in vac. below 80°C (7 Torr); elem. anal.;
|
91% |
|
With
triisobutylaluminum;
In
octane;
under N2 or Ar; vertical ball mill loaded with (AlH3)(n), i-Bu3Al, olefin (molar ratio 1:0.14:4.8) and octane; heated gradually to 100°C with stirring; cooled; stored at 90-100°C for 2 h; balls and blend sepd.; residue washed with octane; filtrate evapd. at 80-90°C (7 Torr); elem. anal.;
|
88.6% |
|
With
Na(i-Bu)3AlH;
In
octane;
under N2 or Ar; mixt. of (AlH3)(n), Na(i-Bu)3AlH (molar ratio 1:0.24) and octane heated to 80°C for 1 h; olefin added; temp. spontaneously raised to 100°C for 20 min; cooled; olefin additionally added dropwise at 90°C for 0.5-1 h; filtered; solvent and excess olefin distd. off in vac. below 80°C(7 Torr); mixt. of (C8H17)3Al and NaAl(C8H17)4 obtained; elem. anal.;
|
-
-
7784-21-6
aluminum hydride
-
-
111-66-0,25068-25-1
oct-1-ene
-
-
1070-00-4
trioctylaluminum
| Conditions | Yield |
|---|---|
|
With
lithium aluminium tetrahydride; aluminium trichloride;
In
octane;
byproducts: LiCl; under N2 or Ar; mixt. of γ-AlH3, excess LiAlH4, octane and olefin heated to 100-110°C for 1 h; additional olefin added at 90-100°C for 2 h; filtered; solvent and excess olefin removed in vac. at 60-70°C (1Torr); AlCl3 added; heated at 80°C; filtered; elem. anal.;
|
89% |
2.What is the CAS number for TRI-N-OCTYLALUMINIUM ?
The CAS number of TRI-N-OCTYLALUMINIUM is 1070-00-4.
More information of TRI-N-OCTYLALUMINIUM 1070-00-4 are:
|
CAS?Number |
1070-00-4 |
|
Density |
0.701 g/mL at 25 °C |
|
Melting Point |
<-40 °C |
|
Boiling Point |
126.4oC at 760mmHg |
|
Flash Point |
-6 °F |
|
Vapor Pressure |
1hPa at 25℃ |
|
HS CODE |
29310099 |
|
PSA |
0.00000 |
|
LogP |
9.94350 |
3.What are another words for TRI-N-OCTYLALUMINIUM ?
Synonyms?for?TRI-N-OCTYLALUMINIUM 1070-00-4:Trioctylaluminum;Aluminum, trioctyl-;Trioctylalane;
4.What is the molecular formula of TRI-N-OCTYLALUMINIUM?
The chemical formula of ?TRI-N-OCTYLALUMINIUM is?C24H51Al which containing 24 Carbon atoms,51 Hydrogen atoms and 1 Aluminum atoms,and the molecular weight of??TRI-N-OCTYLALUMINIUM?is 366.65.
5.What is TRI-N-OCTYLALUMINIUM (1070-00-4) used for?
InChI:InChI=1/3C8H17.Al/c3*1-3-5-7-8-6-4-2;/h3*1,3-8H2,2H3;/rC24H51Al/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3
Relevant articles related to TRI-N-OCTYLALUMINIUM:
|
Article |
Source |
|
One-step synthesis of trialkylaluminum derivatives and dialkylaluminum hydrides by the reaction of alkaline metal aluminum hydrides with α-olefins and alkylaluminum chlorides |
Gavrilenko , p. 168 - 169 (2003) |
|
Insertion, elimination and isomerisation of olefins at alkylaluminium hydride: An experimental and theoretical study |
Weliange, Nandita M.,McGuinness, David S.,Gardiner, Michael G.,Patel, Jim , p. 15286 - 15296 (2015) |
6.Buy TRI-N-OCTYLALUMINIUM with the best price .
Tianjin Tianhan Chemicals Co.,Ltd is a quality supplier of TRI-N-OCTYLALUMINIUM. Our main goal is customer satisfaction. Contact us to negotiate the best price for your business on TRI-N-OCTYLALUMINIUM 1070-00-4.