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5-Methyl-1H-benzotriazole
  • Chemical Name: 5-Methyl-1H-benzotriazole
  • CAS No.: 136-85-6

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1.What is the 5-Methyl-1H-benzotriazole ?

5-Methyl-1H-benzotriazole was used in determination of benzothiazoles and benzotriazoles in waste water samples by GC-MS. It is also used as a potential nitrification inhibitor of urea fertilizer in agricultural soils.

4-methyl-1,2-diaminobenzene
496-72-0

4-methyl-1,2-diaminobenzene

5<sup>(6)</sup>-methylbenzotriazole
136-85-6

5(6) -methylbenzotriazole

Conditions
Conditions Yield
With K10 Montmorillonite Clay; sodium nitrite; In neat (no solvent, solid phase); at 110 ℃; for 1h; Microwave irradiation; Green chemistry;
98%
With tert.-butylnitrite; In acetonitrile; at 27 - 29 ℃; for 0.25h;
93%
With acetic acid; In water; at 70 - 80 ℃; for 0.533333h;
80%
With toluene-4-sulfonic acid; In methanol; at 0 - 20 ℃; for 1h; Inert atmosphere;
73%
With potassium nitrite; sulfuric acid; water;
With sulfuric acid; water; sodium nitrite;
With hydrogenchloride; water; sodium nitrite;
With hydrogenchloride; potassium nitrite; water;
Multi-step reaction with 3 steps
1: 77 percent / benzene / 1 h / Heating
2: conc. HCl, NaNO2 / H2 O / 1 h / Ambient temperature
3: conc. HCl / 2 h / Heating
With hydrogenchloride; sodium nitrite; In water; benzene;
1-azido-2-bromo-4- methylbenzene

1-azido-2-bromo-4- methylbenzene

5<sup>(6)</sup>-methylbenzotriazole
136-85-6

5(6) -methylbenzotriazole

Conditions
Conditions Yield
With n-butyllithium; In tetrahydrofuran; hexane; at -85 - 20 ℃;
87%

2.What is the CAS number for 5-Methyl-1H-benzotriazole ?

The CAS number of 5-Methyl-1H-benzotriazole is 136-85-6.

More information of 5-Methyl-1H-benzotriazole 136-85-6 are:

CAS?Number

136-85-6

Density

1.273 g/cm3

Melting Point

80-82 °C(lit.)

Boiling Point

289.3 °C at 760 mmHg

Flash Point

137.4 °C

Vapor Pressure

0.001Pa at 25℃

Refractive Index

1.5341 (estimate)

HS CODE

Oral rat LD50: 1600 mg/kg

PSA

41.57000

LogP

1.26630

Pka

8.74±0.40(Predicted)

3.What are another words for 5-Methyl-1H-benzotriazole ?

Synonyms?for?5-Methyl-1H-benzotriazole 136-85-6:1H-Benzotriazole,5-methyl- (8CI,9CI);Benzotriazole, 5-methyl- (6CI,7CI);5-Methyl-1,2,3-benzotriazole;5-Methyl-1H-benzo[d][1,2,3]triazole;5-Methylbenzotriazole;5-Tolyltriazole;6-Methyl-1,2,3-benzotriazole;6-Tolyltriazole;Tolutriazole;

4.What is the molecular formula of 5-Methyl-1H-benzotriazole?

The chemical formula of ?5-Methyl-1H-benzotriazole is?C7H7N3 which containing 7 Carbon atoms,7 Hydrogen atoms and 3 Nitrogen atoms,and the molecular weight of??5-Methyl-1H-benzotriazole?is 133.153.

5.What is 5-Methyl-1H-benzotriazole (136-85-6) used for?

5-Methyl-1H-benzotriazole, a member of the benzotriazole class, is a cream to beige crystalline powder that is substituted by a methyl group at position 5. It is an active component in various applications due to its ability to prevent corrosion and its potential as a nitrification inhibitor.

InChI:InChI=1/2C7H7N3/c1-5-2-3-6-7(4-5)9-10-8-6;1-5-3-2-4-6-7(5)9-10-8-6/h2*2-4H,1H3,(H,8,9,10)

Relevant articles related to 5-Methyl-1H-benzotriazole:

Article

Source

Synthesis of Structurally Diverse Benzotriazoles via Rapid Diazotization and Intramolecular Cyclization of 1,2-Aryldiamines

Faggyas, Réka J.,Sloan, Nikki L.,Buijs, Ned,Sutherland, Andrew

, p. 5344 - 5353 (2019/05/21)

Selective Synthesis of N-H and N-Aryl Benzotriazoles by the [3 + 2] Annulation of Sodium Azide with Arynes

Guin, Avishek,Gaykar, Rahul N.,Bhattacharjee, Subrata,Biju, Akkattu T.

, p. 12692 - 12699 (2019/10/11)

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